CdTe/CdS核壳量子点的合成及表征Synthesis and Characterization of CdTe/CdS Core-Shell Quantum Dots
卓宁泽;姜青松;张娜;朱月华;刘光熙;王海波;
ZHUO Ningze;JIANG Qingsong;ZHANG Na;ZHU Yuehua;LIU Guangxi;WANG Haibo;Research Institute of Electric Light Source Materials;College of Materials Science and Engineering;
摘要(Abstract):
本文利用自组装法,以CdTe量子点为模板,合成出CdTe/CdS核壳量子点。研究了不同CdTe/CdS摩尔比时所合成核壳量子点的特性,利用PL荧光光谱、XRD衍射分析、TEM透射电镜对CdTe/CdS核壳量子点进行了分析表征,结果表明:合成核壳量子点结构中没有单独存在的CdS量子点生成,尺寸大约为6nm与理论计算结果相近,在CdTe/CdS的摩尔比=5∶1时,样品具有最大的荧光量子效率32%,具有在重金属离子检测和生物标记中应用的潜在价值。
In this paper,the Cd Te / Cd S core shell quantum dots were synthesized by using self assembly method while Cd Te quantum dots was used as templates. The characteristics of core shell quantum dots with different Cd Te / Cd S molar ratios were studied. PL fluorescence spectra,XRD diffraction analysis,TEM transmission electron microscopy were used to characterize and analysis. The results show that the quantum dot structure of the core is generated by there is no Cd S QDs in the synthesized Cd Te / Cd S core shell quantum dots,the size is about 6nm which close to theoretical calculation,the photoluminescence quantum yields reaches the maximum of 32% when Cd Te / Cd S = 5 ∶ 1,which with value of the application in the detection of heavy metal ions and biological markers.
关键词(KeyWords):
CdTe量子点;CdTe/CdS量子点;核壳结构;荧光量子效率
CdTe quantum dots;CdTe / CdS quantum dots;core-shell structure;photoluminescence quantum yields
基金项目(Foundation): 国家高技术研究发展计划(863计划)(批准号:2011AA03A107);; 江苏省科技成果转化计划(批准号:BA2014073)资助
作者(Authors):
卓宁泽;姜青松;张娜;朱月华;刘光熙;王海波;
ZHUO Ningze;JIANG Qingsong;ZHANG Na;ZHU Yuehua;LIU Guangxi;WANG Haibo;Research Institute of Electric Light Source Materials;College of Materials Science and Engineering;
参考文献(References):
- [1]WANG Qisui,FANG Tingting,LIU Peng,et al.Study of the bioeffects of Cd Te quantum dots on Escherichia coli cells[J].Journal of Colloid&Interface Science,2011,363(2):476-480.
- [2]崔一平,韩旭东,王著元,等.量子点发光材料及其在照明光源器件中的应用[J].照明工程学报,2005,16(1):11-14.
- [3]MEDINTZ I L,CLAPP A R,MATTPISSI H,et al.Selfassembled nanoscale biosensors based on quantum dot FRET donors[J].Nature Materials,2003,2(9):630-638.
- [4]KONESWARAN M,Narayanaswamy R.l-Cysteine-capped Zn S quantum dots based fluorescence sensor for Cu2+ion[J].Sensors&Actuators B Chemical,2009,139(1):104-109.
- [5]翟保才,张文君,吴奉炳,等.半导体量子点电致发光器件用于航空舱内照明的可行性研究[J].照明工程学报,2013,24(2):92-96.
- [6]ROSSETTI R,BRUS L E.Electron-hole recombination emission as a probe of surface-chemistry in aqueous Cd S colloids[J].Journal of Physical Chemistry,1982,86(23):4470-4472.
- [7]FU H,ZUNGER A,FU H.In P quantum dots:Electronic structure,surface effects,and the redshifted emission[J].Physical Review B Condensed Matter,1997,56(3):1496-1508.
- [8]WANG Y,SUNA A,MCHUGH J,et al.Optical transient bleaching of quantum-confined Cd S clusters:The effects of surface-trapped electron-hole pairs[J].Journal of Chemical Physics,1990,92(11):6927-6939.
- [9]LU Jiangquan,LU Shiyan,YE Tai,et al.Synthesis of Multifunctional Mn-Doped Cd Te/Zn S Core/Shell Quantum Dots[J].Chinese Journal of Chemistry,2011,29(11):2308-2314.
- [10]WARGNIER R,BARANOV A V,MASLOV V G,et al.Energy Transfer in Aqueous Solutions of Oppositely Charged Cd Se/Zn S Core/Shell Quantum Dots and in Quantum Dot-Nanogold Assemblies[J].Nano Letters,2004,4(3):451-457.
- [11]LIU Yusan,SUN Yinghua,VEINIER P T,et al.p Hsensitive Photoluminescence of Cd Se/Zn Se/Zn S Quantum Dots in Human Ovarian Cancer Cells.[J].Journal of Physical Chemistry C,2007,111(7):2872-2878.
- [12]CHEN Yongfen,JAVIER V,HAN H,et al.Giant multishell Cd Se nanocrystal quantum dots with suppressed blinking[J].Journal of the American Chemical Society,2008,130(15):5026-5027.
- [13]赵艳,孙雪花,高楼军.Cd Te/Cd S量子点荧光探针测定痕量锑[J].分析科学学报,2014,30(4):554-556.
- [14]姜青松,朱月华,邢海东,等.Cd Te量子点生长速率的参数研究[J].人工晶体学报,2014,43(8):1981-1985.
- [15]CROSBY G A,DEMAS J N.Measurement of photoluminescence quantum yields.J Phys Chem[J].Journal of Physical Chemistry,1971,75(8):991-1024.
- [16]YU W W,QU L,GUO W,et al.Experimental Determination of the Extinction Coefficient of Cd Te,Cd Se and Cd S Nanocrystals[J].Chemistry of Materials,2004,15(14):2854-2860.
- CdTe量子点
- CdTe/CdS量子点
- 核壳结构
- 荧光量子效率
CdTe quantum dots - CdTe / CdS quantum dots
- core-shell structure
- photoluminescence quantum yields
- 卓宁泽
- 姜青松
- 张娜
- 朱月华
- 刘光熙
- 王海波
ZHUO Ningze- JIANG Qingsong
- ZHANG Na
- ZHU Yuehua
- LIU Guangxi
- WANG Haibo
- Research Institute of Electric Light Source Materials
- College of Materials Science and Engineering
- 卓宁泽
- 姜青松
- 张娜
- 朱月华
- 刘光熙
- 王海波
ZHUO Ningze- JIANG Qingsong
- ZHANG Na
- ZHU Yuehua
- LIU Guangxi
- WANG Haibo
- Research Institute of Electric Light Source Materials
- College of Materials Science and Engineering