朱雨轩,杨波波,郭春凤,胡蓉蓉,鲁青,杨雪舟
ZHU Yuxuan,YANG Bobo,GUO Chunfeng,HU Rongrong,LU Qing,YANG Xuezhou

• 1:上海应用技术大学理学院
• 2:上海灯钦光电科技有限公司
• 3:宁波朗格照明电器有限公司

摘要(Abstract)：

铅基钙钛矿量子点具有许多优异的物理和化学性质,其光致发光产率甚至可以达到90%以上,但是铅毒性和稳定性不佳的问题限制了铅基钙钛矿量子点商业化的发展。基于此,使用其他无毒的金属元素替代铅元素制备在空气中高稳定性的无铅钙钛矿量子点具有十分重要的意义。本文综述了Bi基无铅钙钛矿量子点的制备及其应用的研究进展以及未来的研究重点。
Lead-based perovskite quantum dots have many excellent physical and chemical properties, and their photoluminescence yield can even reach more than 90%, but the problems of lead toxicity and poor stability limit the commercialization of lead-based perovskite quantum dots. Based on this, the use of other non-toxic metal elements instead of lead elements to prepare lead-free perovskite quantum dots with high stability in air will be of great significance. This paper summarizes the research progress of the preparation and application of Bi-based lead-free perovskite quantum dots, as well as the future research focus.

关键词(KeyWords)： 无铅;Bi基;钙钛矿量子点
lead-free;Bi-based;perovskite quantum dots

Abstract:

Keywords:

基金项目(Foundation): 浙江省科技计划重点研发计划(2018C01046)

作者(Author): 朱雨轩,杨波波,郭春凤,胡蓉蓉,鲁青,杨雪舟
ZHU Yuxuan,YANG Bobo,GUO Chunfeng,HU Rongrong,LU Qing,YANG Xuezhou

参考文献(References)：

• [1] WAID P,TANISHIMA S,Agency I E.Light’s labour’s lost:policies for energy-efficient lighting[J].Organization for Economic,2006(343):14-15.
• [2] CRAWFORD M H.LEDs for solid-state lighting:Performance challenges and recent advances[J].IEEE Journal of Selected Topics in Quantum Electronics,2009,15(4):1028-1040.
• [3] 王伟，邹军，张灿云，等.LED器件热管理分析方法及其应用[J].应用技术学报，2019,19(1):52-59.
• [4] 钱幸璐，石明明，邹军，等.大功率LED灯具研究进展[J].应用技术学报，2018,18(1):26-30.
• [5] 王子明，邹军，张灿云，等.白光LED用荧光玻璃的制备方法及应用研究进展[J].应用技术学报，2018,18(1):72-80.
• [6] SCHUBERT E F.Solid-state light sources getting smart[J].Science,2005,308(5726):1274-1278.
• [7] 刘祎明，邹军，李文博，等.荧光薄膜的制备方法及其在LED中的应用[J].应用技术学报，2017,17(3):207-212.
• [8] 郭伟玲.基于LED的半导体照明与超越照明进展[J].照明工程学报，2019,30(1):3.
• [9] ANDREEV A D,KOLOBKOVA E V,LIPOVSKII A.Optical absorption in PbSe spherical quantum dots embedded in glass matrix[J].Journal of Applied Physics,2000,88(2):750-757.
• [10] CHUNG W,PARK K,YU H J,et al.White emission using mixtures of CdSe quantum dots and PMMA as a phosphor[J].Optical Materials,2010,32(4):515-521.
• [11] CAO Y,WANG N,TIAN H,et al.Perovskite light-emitting diodes based on spontaneously formed submicrometre-scale structures[J].Nature,2018,562(7726):249-253.
• [12] 柏皓文，吴江，杨阳，等.不同摩尔比的CsPbBr3钙钛矿量子点微晶发光性能[J].照明工程学报，2020,31(1):27-30.
• [13] 何思宇，刘远海，蒋福春，等.氧化物薄膜抑制量子点的光衰性能[J].照明工程学报，2020,31(1):36-39.
• [14] KUMAR S,JAGIELSKI J,KALLIKOUNIS N,et al.Ultra-pure green light emitting diodes using two-dimensional formamidinium perovskites:achieving rec.2020 color coordinates[J].Nano Letters,2017,17(9):5277-5284.
• [15] TAKAYUKI,CHIBA,YUKIHIRO,et al.Anion-exchange red perovskite quantum dots with ammonium iodine salts for highly efficient light-emitting devices[J].Nature photonics,2018,12:681-687.
• [16] BEGUM R,PARIDA M R,ABDELHADY A L,et al.Engineering interfacial charge transfer in CsPbBr3 perovskite nanocrystals by heterovalent doping[J].Am.Chem.Soc.,2016,139(2):731-737.
• [17] AKKERMAN Q A,INNOCENZO V D,ACCORNERO S,et al.Tuning the optical properties of cesium lead halide perovskite nanocrystals by anion exchange reactions[J].Am.Chem.Soc.,2015,137(32):10276-10281.
• [18] SONG Jizhong,LI Jianhai,LI Xiaoming,et al.Quantum dot light-emitting diodes based on inorganic pervskite cesium lead halides(CsPbX 3)[J].Adv.Mater.,2015,27(44):7162-7167.
• [19] PAN Jun,QUAN Lina,ZHAO Yongbiao,et al.Highly efficient perovskite-quantum-dot light-emitting diodes by surface engineering[J].Adv.Mater.,2016,28(39):8718-8725.
• [20] YASSITEPE E,YANG Z Y,VOZNYY O,et al.Amine-free synthesis of cesium lead halide perovskite quantum dots for efficient Light-Emitting Diodes[J].Adv.Funct.Mater.,2016,26(47):8757-8763.
• [21] LI Xiaoming,YU Dejian,CHEN Jun,et al.Constructing fast carrier tracks into flexible perovskite photodetectors to greatly improve responsivity[J].ACS.Nano.,2017,11(2)2015-2023.
• [22] YAKUNIN S,PROTESESCU L,KRIEG F,et al.Low-threshold amplified spontaneous emission and lasing from colloidal nanocrystals of caesium lead halide perovskites[J].Nat.Commun.,2015,6:1-8.
• [23] DURSUN,SHEN C,PARID M R,et al.Perovskite nanocrystals as a color converter for visible light communication[J].ACS Photonics.,2016,3(7):1150-1156.
• [24] PROTESESCU L,YAKUNIN S,BODNARCHUK M I,et al.Nanocrystals of cesium lead halide perovskites(CsPbX3,X=Cl,Br,and I):novel optoelectronic materials showing bright emission with wide color gamut[J].Nano letters,2015,15(6):3692-3696.
• [25] JELLICOE T C,RICHTER J M,GLASS H F J,et al.Synthesis and optical properties of lead-free cesium tin halide perovskite nanocrystals[J].Journal of the American Chemical Society,2016,138(9):2941-2944.
• [26] PARK B W,PHILIPPE B,ZHANG X,et al.Bismuth based hybrid perovskites A3Bi2I9(A:Methylammonium or Cesium)for solar cell application[J].Advanced Materials,2015,27(43):6806-6813.
• [27] LENG Meiying,CHEN Zhengwu,YANG Ying,et al.Lead-free,blue emitting bismuthhalide perovskite quantum dots[J].Angewandte Chemie International Edition,2016,55(48):15012-15016.
• [28] XIAO Zewen,MENG Weiwei,WANG Jianbo,et al.Searching for promising new perovskite-based photovoltaic absorbers:the importance of electronic dimensionality[J].Materials Horizons,2017,4(2):206-216.
• [29] ZHOU Chenkun,YUAN Zhao,TIAN Yu,et al.Highly luminescent bulk quantum materials based on zero-dimensional organic tin halide perovskites[J].ArXiv E-prints,2017,9(51):44579-44583.
• [30] SUN Shibin,YUAN Dan,XU Yuan,et al.Ligand-mediated synthesis of shape-controlled cesium lead halide perovskite nanocrystals via reprecipitation process at room temperature[J].Acs.Nano.,2016,10(3):3648-57.
• [31] WANG Chuying,ZHANG Yukang,WANG Aifei,et al.Controlled synthesis of composition tunable formamidinium cesium double cation lead halide perovskite nanowires and nanosheets with improved stability[J].Chemistry of Materials,2017,29(5):2157-2166.
• [32] YANG Bin,CHEN Junsheng,HONG Feng,et al.Lead-free,air-stable all-inorganic cesium bismuth halide perovskite nanocrystals[J].Angewandte Chemie International Edition,2017,59(41):12471-12475.
• [33] LENG Meiying,YANG Ying,ZENG Kai,et al.All-inorganic bismuth-based perovskite quantum dots with bright blue photoluminescence and excellent stability[J].Adv.Funct.Mater.,2018,28(1):1704446.1-1704446.11.
• [34] VOLONAKIS G,FILIP M R,HAGHIGHIRAD A A,et al.Lead-free halide double perovskites via heterovalent substitution of noble metals[J].Journal of Physical Chemistry Letters,2016,7(7):1254-1259.
• [35] SLAVNEY A H,HU T,LINDENBERG A M,et al.A bismuth-halide double perovskite with long carrier recombination lifetime for photovoltaic applications[J].Journal of the American Chemical Society,2016,138(7):2138-2141.
• [36]PAN Weicheng,WU Haodi,LUO Jiajun,et al.Cs2AgBiBr6 single-crystal X-ray detectors with a low detection limit[J].Nature Photonics,2017,11:726-732.
• [37] YIN Lixiao,WU Haodi,PAN Weicheng,et al.Controlled cooling for synthesis of Cs2AgBiBr6 single crystals and its application for X-ray detection[J].Advanced Optical Materials,2019,7(19):1900491-1900498.